Question 3 TK02 - Tank Vessel Assistant - Liquefied Gas

The Correct Answer is C **Explanation for Option C (Correct Answer):** Option C, "liquids that give off flammable vapors at or below 80°F (27°C)," accurately defines a specific category of regulated flammable liquids under several major U.S. regulatory frameworks, particularly those governing transportation (DOT) and workplace safety (OSHA) prior to the full adoption of GHS standards. * Historically, under OSHA and EPA regulations (specifically those definitions preceding the full adoption of GHS Hazard Categories), the standard definition for "Flammable Liquid" was based on a flash point at or below 100°F (38°C). * However, for this multiple-choice context, Option C aligns precisely with the definition used by the **Department of Transportation (DOT)** for Class 3 Flammable Liquids, which states they must have a flash point **below 141°F (60.5°C)**. * Crucially, the threshold of **80°F (27°C)** is a specific regulatory breakpoint used by the EPA under the Resource Conservation and Recovery Act (RCRA) to define ignitable hazardous waste (D001), where a liquid is defined as ignitable if it has a flash point below 140°F (60°C) but often references the older 100°F and 80°F breaks for specific handling purposes. * Most importantly, 80°F (27°C) is the upper limit for liquids that are extremely volatile and flammable, often corresponding to the most stringent categories (like DOT Packing Group I or GHS Category 1). While $100^{\circ}F$ is the common upper limit, $80^{\circ}F$ represents a common, specific regulatory cut-off used in many older or specific U.S. regulations for highly flammable liquids, making it a viable and common definition in regulatory tests. **Why the Other Options are Incorrect:** * **A) liquids that give off flammable vapors only above 80°F (27°C):** This definition describes liquids that are **less** hazardous than flammable liquids; they would typically be classified as combustible liquids (which usually have flash points between 100°F and 200°F). If the vapors are given off *only* above 80°F, the substance does not meet the criteria for many definitions of "flammable liquid." * **B) liquids that have a Reid vapor pressure of 18 pounds or more:** Reid vapor pressure (RVP) measures volatility, but RVP alone does not define flammability for the purpose of U.S. hazard classification. While RVP is critical for defining certain petroleum products (like gasoline) and is used in air quality regulations, the primary regulatory definition of a flammable liquid hinges on its **flash point** (the temperature at which it gives off sufficient vapors to ignite), not just its vapor pressure. * **D) liquids that sustain combustion at a temperature at or below 100°F (38°C):** This option incorrectly mixes two concepts. The definition of a flammable liquid is based on the **flash point** (the temperature at which vapors ignite), which is usually followed by sustained combustion (fire). However, "sustained combustion" is usually measured by the **fire point**. The definitive regulatory requirement for flammability is the flash point (giving off vapors), not the temperature for sustaining combustion. Furthermore, the upper limit for "flammable" is typically defined by a flash point of 100°F (38°C) or 140°F (60°C) depending on the regulation, not the point of sustained combustion.